Product ID:S-1 BLACK RIO INK 1300559
MSDS Date:05/15/1989
FSC:7510
NIIN:00N018096
MSDS Number: BKZMN

DIAGRAPH CORPORATION

HERRIN, IL 62948

Emergency Phone: 618-997-3321

Info Phone: 618-997-3321

Preparer: W R MCMILLEN

Cage: FO627

DIAGRAPH CORPORATION

520 HERRIN, IL 62948 US

Telephone: (618) 997-3321

Cage: FO627

DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE)

CAS: 123-42-2

RTECS: SA9100000

Fraction By Weight: 40-60%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM; 9192

PROPYLENE GLYCOL MONOMETHYL ETHER

CAS: 107-98-2

RTECS: UB7700000

Fraction By Weight: 20-40%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL

CAS: 112-34-5

RTECS: KJ9100000

Fraction By Weight: 1-20%

LD50 LC50 Mixture:LD50: ORAL(RAT), 4000 MG/KG. (ING 1).
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: MAY CAUSE DERMATITIS AND
IRRITATION. EYE: MAY CAUSE IRRITATION AND BLURRED VISION.
INHALATION: MAY CAUSE IRRITATION, DIZZINESS, FATIGUE, VOMITING,
DIARRHEA. INGESTION: MAY CAUSE VOMITING, IRRITA TION, AND NAUSEA.
OVEREXPOSURE: MAY CAUSE LIVER AND KIDNEY DAMAGE.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH WATER FOR A
MINIMUM OF 15 MINUTES. CALL PHYSICIAN. INHALATION: PROVIDE FRESH
AIR AND REST. INGESTION: INDUCE VOMITING. CALL PHYSICIAN.

Flash Point Method:CC
Flash Point:97.0F,36.1C
Lower Limits:0.9%
Extinguishing Media:ALCOHOL FOAM, DRY CHEMICAL, CO2.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . A STRAIGHT STREAM OF WATER COULD SPREAD
FIRE.
Unusual Fire/Explosion Hazard:A VAPOR ACCUMULATION WILL FLASH AND/OR
EXPLODE IF IGNITED.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. ABSORB ON
INERT MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY PLACE AWAY FROM ALL
SOURCES OF IGNITION.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:NEEDED TO KEEP VAPOR CONCENTRATION BELOW TLV LEVEL.
Protective Gloves:NON-ABSORBENT GLOVES RECOMMENDED.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:OIL RESISTANT FOOTWEAR. USE PROTECTIVE
CLOTHING AS NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:F4
Boiling Pt:B.P. Text:180F,82C
Vapor Density:HVR/AIR
Spec Gravity:0.9984
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Appearance and Odor:BLACK LIQUID, SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND CAUSTIC MATERIAL.
Stability Condition to Avoid:NONE. REACTIVITY: AVOID OPEN FLAMES AND
SPARKS.
Hazardous Decomposition Products:CO2, CO, HYDROCARBONS.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE, AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.